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In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.  相似文献   
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Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi3O8), as well as the Schottky defect energy for the removal of a Na2O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.  相似文献   
66.
This paper presents a computer investigation extending to the case of parabolic orbits, an earlier investigation conducted by Barricelli and Metcalfe (1969) on lunar impacts by external low eccentricity satellites as a means to interpret the asymmetric distribution of lunar maria. Parabolic orbits can be approximated by two kinds of objects:
  1. High eccentricity external satellites may, near periapsis, approach the Moon with orbital velocity and other characteristics closely resembling those of a parabolic orbit.
  2. Asteroids and meteoroids approaching the Earth-Moon system with a low velocity may have moved in a nearly parabolic orbit when they reached the lunar distance from the Earth at the time when the impacts which carved the lunar maria took place.
The investigation gives, therefore, not only additional information relevant to the interpretation of the distribution of lunar maria by the satellite impacts hypothesis (in this case high eccentricity ones), but also information about the alternative hypothesis (Wood, 1973) that asteroid impacts rather than satellite impacts were involved.  相似文献   
67.
The short-term effects of the commercial PBDE flame retardant mixtures Penta-BDE and cta-BDE on the expression of cytochrome P450 1A (CYP1A), vitellogenin (Vtg) and zona radiata proteins (Zrp) were investigated in juvenile salmon (Salmo salar). For this purpose, groups of fish were dosed twice (oral intake at days I and 4) with 10 and 50 mg/kg body weight of both commercial mixtures. The fishes were sacrificed at day 7 (n = 5 for each group) and 14 (n = 6 for each group), and blood, liver, fillet, and brain were collected. Blanks and positive controls were also part of the experiment. The expressions of Vtg, Zrp, and CYPIA were measured with several techniques (EROD, ELISA, Western, Northern and Slot Blot). The values in the groups of fish treated with Penta-BDE or Octa-BDE did not significantly differ from the reference group for any of the parameters tested. In contrast, the positive control groups treated with estradiol-17beta for Vtg and Zrp expression, and beta-naphthoflavone for CYP1A expression did show a significant response, indicating the potential sensitivity of the fishes for the parameters measured. Since the results of the chemical analyses showed concentrations of a number of PBDE congeners in liver, fillet, and brain that were about three orders of magnitude above those of fish from the North Sea, it is concluded that the short-term toxicity of both commercial PBDE mixtures for these endpoints was low.  相似文献   
68.
Subsurface sediments from a pockmark area in South-Western Barents Sea have been earlier found to contain elevated levels of petroleum-related polycyclic aromatic hydrocarbons. This work describes a comprehensive analysis of various biomarkers, including the highly source-specific hopanes, in a 4.5?m long gravity core from the same area, together with subsurface sediment samples from other areas in the region without pockmarks present ("background samples"). A clear difference between the pockmark gravity core and the background sediment cores was found, both with regard to genesis and the level of transformation of organic matter. A number of indicator parameters, such as methylphenanthrene index (MPI-1), point towards a significantly higher maturity of hydrocarbons in the pockmark core throughout its length as compared to the other sampled locations. Higher contents of microbial hopanoids (hopenes) may indicate the former presence of petroleum. These findings confirm the hypothesis of a natural hydrocarbon source in the deeper strata present in the studied location with pockmarks.  相似文献   
69.
Four drift accumulations have been identified on the continental margin of northern Norway; the Lofoten Drift, the Vesterålen Drift, the Nyk Drift and the Sklinnadjupet Drift. Based on seismic character these drifts were found to belong to two main groups; (1) mounded, elongated, upslope accretion drifts (Lofoten Drift, Vesterålen Drift and Nyk Drift), and (2) infilling drifts (Sklinnadjupet Drift). The drifts are located on the continental slope. Mainly surface and intermediate water circulation, contrary to many North Atlantic and Antarctic drifts that are related to bottom water circulation, and sediment availability have controlled their growth. Sediments were derived both from winnowing of the shelf and upper slope and from ice sheets when present on the shelf. The main source area was the Vøring margin. This explains the high maximum average sedimentation rate of the nearby Nyk (1.2 m/ka) and Sklinnadjupet (0.5 m/ka) Drifts compared with the distal Lofoten (0.036 m/ka) and Vesterålen (0.060 m/ka) Drifts. The high sedimentation rate of the Nyk Drift, deposited during the period between the late Saalian and the late Weichselian is of the same order of magnitude as previously reported for glacigenic slope sediments deposited during glacial maximum periods only. The Sklinnadjupet Drift is infilling a paleo-slide scar. The development of the infilling drift was possible due to the available accommodation space, a slide scar acting as a sediment trap. Based on the formation of diapirs originating from the Sklinnadjupet Drift sediments we infer these sediments to have a muddy composition with relatively high water content and low density, more easily liquefied and mobilised compared with the glacigenic diamictons.  相似文献   
70.
In an attempt to learn more about the cytochrome P450 (CYP) system of mussels, we used protein databases and alignment software to extract highly conserved CYP sequences. From these alignments synthetic peptides were produced and used for rabbit immunisation, which yielded polyclonal antibodies against the CYP families 2 and 4. The antibodies were evaluated with Western Blot and ELISA assays, using digestive gland microsomal samples from the mussel Mytilus edulis. Western Blots revealed immunoreactions for both antibodies. The anti-CYP2 sequence rendered one major immunopositive protein of approximately 49 kDa size, and weak signals for proteins of approximately 41 and 56 kDa size. The anti-CYP4 sequence rendered two major bands of approximately 56 and 59 kDa size, and also a weak immunoreaction with a protein of approximately 43 kDa size. ELISA rendered only weak signals even with a 1:50 dilution of IgG-purified serum. A 10-day exposure to Aroclor 1254 did not appear to affect any of the immunopositive proteins, while total PCBs in soft bodies increased from 14-40 ng/g DW in controls to 373-638 ng/g DW in exposed mussels.  相似文献   
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